Tissue World Magazine
 

 
CHEMICALS

CHEMICALS FOR PROGRESS
It is hard to overestimate the importance of chemicals in tissue production and converting. In response to TW invitation, several companies outline their latest innovations


Nalco micro-programs replace RDF
By Larry Bonday


Traditional retention drainage and formation (RDF) chemistries create difficulty in controlling the yankee coating. This, combined with the perceived impact to softness and absorbency, can result in the underuse of these RDF chemistries in tissue and towel grades. Today's new microparticle and micro-polymer programs are tailored directly to the machine's operating condition and product quality specifications. This eliminates tissue makers' concerns with traditional RDF chemistries.

New micro-particle and micro-polymer programs developed by Nalco Company deliver the cost savings of traditional RDF programs, while at the same time improving the process stability of both the wet end of the machine and the yankee coating. The cost savings are due to improvement in fibre yield and the reduction in use of process and functional chemistries. The improved wet end stability obtained from these new RDF programs typically results in less frequent and less severe upset conditions on the machine. The improved yankee coating performance translates into improved creping efficiency, improved sheet properties, and lower yankee coating addition rates.

The proven ability of Nalco Company to tailor new RDF programs directly to the machine operating conditions and product quality specifications means that the tissue maker can produce any range of high softness toilet paper or high absorbency towel while still enjoying the benefits of improved machine stability and lower operating cost. Larry Bonday is Program Manager, Tissue Towel Grades, Paper Service Division, Nalco Company.

Plasticizing release: a new approach
By Chris Rozett

Amazon Papyrus is launching a line of oil-free, plasticizing release agents for tissue creping. Some reasons to make the switch to a plasticizing release include high oil prices, uneven yankee temperature profiles, increased use of acacia furnish and difficult-to-coat Yankees.


There are two major ways in which plasticizers excel as release agents:
Oil-based releases migrate away from the hot dryer surface, giving a concentration gradient in the Z direction of the coating matrix. Plasticizing release agents, on the other hand, dehydrate along with the adhesive in the coating matrix. There is a minimal gradient across the thickness of the coating. This gives a more uniformly softened coating with minimal hard coating buildup. The graphic shows the potential relative release concentrations in the coating matrix for oil-based and plasticizing release agents.
Plasticizers work to soften the coating matrix without stripping the coating off the dryer. They help to build up the coating thickness, which allows mills to reduce the amount of creping adhesive used. The result is a soft, bulky coating that gives good yankee and blade protection while maximizing sheet softness.

Chris Rozett is Technical Marketing Manager with Amazon Papyrus Chemicals.

Trio of Buckman innovations

Buckman has created the MAGNOS™ product line of yankee coating chemicals specifically for the ATMOS premium tissue technology developed by our partner Voith. The key benefits are improved sheet transfer and uniform adhesion of the structured sheet to the yankee cylinder surface and finely-tuned creping control resulting in better machine runnability and premium tissue properties. In support of the MAGNOS chemistries, complementary products are available, including wet end chemistry control, fibre-modification enzymes, Optimyze® enzymatic stickies control and fabric care, and process water treatment.

A second innovation from the company is the new SELECT yankee dryer adhesive system, which provides coating optimization never before achievable with yankee dryer packages.

SELECT uses a relatively hard and robust hybrid first adhesive to provide uniform coating and superior yankee dryer protection plus high bond strength between the coating and the sheet at the doctor blade. A second soft rewettable coating is used to increase sheet attachment at the pressure roll. Buckman currently has a selection of adhesives to meet varying process demands.

The third innovation consists of recently-developed enzyme products Buzyme 2535 and 2523S, which were created specifically to condition the fibre - particularly virgin softwood fibre and recycled fibre - before it is refined. This treatment can improve bonding strength, enhance the refining process, and reduce expensive fibre usage, as well as increase tensile, reduce porosity, and improve coating holdout.

EDT enzymes for cost savings


As energy costs continue to climb, recycled tissue producers are seeking ways to reduce energy use. Enzymatic Deinking Technologies (EDT) offers innovative, mill-tailored solutions to this growing problem. With the use of EDT's products, natural enzyme mechanisms can be leveraged to improve the papermaking process which can result in substantial reductions in energy use. EDT's Enzynk® and Refinase® products have enabled mills to improve tissue/towel production, increasing quality while offering multiple strategies to reduce energy through increased pulper defiberization, greater tonnage output, reduced refining, and reduced drying energy.

One of our applications enhances pulper action in breaking down the fibre matrix. This approach shortens pulping time, which decreases energy use, as pulping is one of the most energy-intensive stages in a deink plant. For mills that are bottlenecked at the pulper, this method is also instrumental in increasing output. Enhanced fibre yield through reduced fine screen rejects has also been observed.

Enzymatic deinking has further helped mills increase production rates while maintaining deinked pulp quality, notably reducing specific energy cost per ton produced. Energy use is not a fully variable cost. Many EDT customer applications focus on this type of fibre modifications that enhance drainage and increase total output.

In the same vein, EDT uses enzymatic treatments to 'clean' fibres to be more conducive to hydrogen bonding, thus strengthening the sheets. Because final tissue sheet strength is an important driver for the level of refining energy imparted to the stock, mills can decrease refining energy without compromising sheet strength and can also consider options to degrade furnish use and cost to varieties that would provide less strength. Also significant in driving energy use per ton are dewatering and drying dynamics. EDT uses enzymatic treatments to enhance stock drainability and allow steam to escape more readily, thereby reducing energy use on the machine.

Altogether, the advantages of these tailored enzymatic approaches have proven to be considerable, saving mills over $15/ton in energy, and are likely to remain important options as energy costs continue to rise.

Innovation across the range

Hercules' well known range of Kymene® wet strength resins has been enhanced by several new offerings in 2008. Kymene® 920, available in Europe and North America, meets Generation 2 regulatory standards for epi-residuals whilst offering Generation 1 wet strength resin performance. Additionally, in Europe only, Kymene® 227LXP and Kymene® 33VSP offer Hercules' highest ever functionality in the ultra low AOX and Generation 3 wet strength categories respectively, due to a unique proprietary manufacturing process.

In yankee coating, Hercules has introduced a range of 'plasticized' Crepetrol® base coats globally to address the requirements of low moisture or aggressive recycled fibre tissue manufacture without hard coating buildup. This is augmented by a new patented polymer high temperature base coat in North America and later this year in Europe as well as the availability of laboratory crepe performance modeling for customers via our three regional applications laboratories in North America, Europe and Asia. Additionally in 2008, Hercules introduced a range of Dimension™ converting technology. Boosting the value of tissue products is a primary concern in today's competitive market. The Dimension™ converting range comprises three remarkable technologies that offer papermakers new opportunities in the areas of tissue lotions, biodegradable tissue for use with septic tank systems, and converting adhesives.

Finally, Hercules' process chemistries in the field of contaminant control and microbiological control continue to evolve with new generation DeTac® pitch and stickies control and expansion of the market leading Spectrum® ammonium bromide control into new geographies.

Cargill fibre additives for better strength

Cargill is coming out with a line of enhanced fibre additives designed to increase the strength of tissue and towel products while lowering manufacturing costs. Sourced from renewable agricultural seed fibres and made using a totally chlorine-free (TCF) process, the soon-to-be-branded product line presents an alternative to the typical chemical approaches for achieving the tissue strength properties desired by consumers. The high hemicellulose composition of Cargill's enhanced fibre additives improves fibre-to-fibre bonding. This enhances the strength of the paper sheet (wet and dry tensile) and provides a tool for tissue makers to optimize fibre furnish increase paper machine productivity, minimize refining requirements, reduce wet end chemical usage and lower overall manufacturing costs. A reduction in refining adds additional benefits for increased bulk and improved softness in tissue grades.

Cargill conducted a number of customer trials over a wide range of grades before deciding to build a manufacturing facility in Cedar Rapids, Iowa. Production is expected to start in November.

For more information, contact Cargill at +1 952 742-4332.

AROSURF®PA 873 tissue softener

The new AROSURF®PA 873 from Evonik Goldschmidt GmbH is suitable for virgin, low strength, and recycled fibres. AROSURF®PA-873 is a universally compatible, highly concentrated liquid, recommended as an overspray softener for tissue at the felt, on the yankee, or after sheet formation. The new softener can be dispersed with an in-line mixer immediately before spray application. Aqueous dispersions at 5-10% of AROSURF® PA-873 have low viscosity and are easily applied by spray boom. The pick-up varies, according to the desired softness, from 0.5-5% product on tissue weight.

AROSURF® PA-873 imparts a soft handfeel (surface softness) and does not have significant influence on tensile strength or water absorbency. It is based on vegetable and synthetic raw materials and does not contain solvents or VOCs. It is food contact compliant in line with FDA 21 CFR § 176.210. Due to its mild ingredients, it does not require a hazard warning label in line with EC directives on dangerous materials. It is listed on the following inventories: EINECS, TSCA, Canada (DSL), Japan (ENCS), Australia (AICS), Philippines (PICCS), China. The product has a shelf life of 12 months and is on current production.

Clariant's Cartaspers® PSM for stickies control

Cartaspers PSM® Liquid is a new polymer designed for stickies control in the tissue manufacturing process. This water-based, non-ionic polyester dispersion reduces the build-up of stickies in the wet end and on felt/wire fabrics.

In a wet-end application Cartaspers PSM Liquid has a strong affinity for the hydrophobic stickies and works by encapsulating the stickies preventing them from agglomerating. In a wire or felt treatment application, it forms a mono-molecular hydrophilic 'coating' over the synthetic fibres and prevents stickies from adsorbing onto the wire or felt.

Cartaspers PSM Liquid readily biodegrades and is compatible with most cationic and anionic chemical additives. This FDA-compliant product can be part of your green initiative since Cartaspers PSM Liquid received the prestigious P2 Recognition Project Award from the US Environmental Protection Agency as an innovative new pollution-preventing product.

For more information, call +1-800-727-3710 or email: paperexpert@clariant.com.